Yes, given that both are mathematically lossless, conversion is lossless too.
The reason for this is that the signal can always be reconstructed to its original form when a FLAC/ALAC file is decoded. Thus, they are equivalent and you should experience no loss when transcoding — even when transcoding multiple times.
The only error I could imagine would be an arithmetical one, e.g. through limited floating point precision in calculations. I don't think this applies to either FLAC or ALAC.
In case you only use a "psychoacoustically" lossless codec, this is not possible. Lossless in a psychoacoustic sense would mean that you can't distinguish the original and the compressed version, yet they are very different from each other. MP3 or MPEG-4 AAC use various psychoacoustic techniques to achieve this. Thus, when transcoding, the original version can't be reconstructed and you'd experience a loss of quality.
In case you want to convert ALAC to FLAC, ffmpeg would be a good option, as it's free and available for almost every platform.
ffmpeg -i audio.m4a -c:a flac audio.flac
FFmpeg will read ALAC without issues. For *nix systems, there's also a script called Convert to FLAC which makes the whole process easier. With Bash you could simply convert all files in a single directory as well:
for f in *.m4a; do ffmpeg -i "$f" -c:a flac "${f%.m4a}.flac"; done
Note: If you get a message about ffmpeg being deprecated, this is actually not the case – it's still an actively developed program. However, Ubuntu's package maintainers just decided to switch to the Libav fork of FFmpeg and thus supply you with avconv instead of ffmpeg. The version of ffmpeg available on Ubuntu is therefore outdated. You can get a recent one by downloading a static build instead, or compiling it yourself. Read on for more info: Who can tell me the difference and relation between ffmpeg, libav, and avconv
Best Answer
ImgBurn is a free CD burning software and it supports the FLAC audio format amongst others (AAC, APE, M4A, MP3, MP4, MPC, OGG, PCM, WAV, WMA and WV).
ImgBurn is often recommended on SuperUser and on other sites (LifeHacker for instance) for all its features.