I'm not sure here, but I'm going to go out on a limb. I think your issue might be with your DENY CONTROL record. See here about half way down the page:

Denying CONTROL permission on a database implicitly denies CONNECT permission on the database. A principal that is denied CONTROL permission on a database will not be able to connect to that database.

I realize that example is for a database, but take it one more granual level. A DENY CONTROL on a table will deny all privileges on it, I'm guessing. Do a REVOKE CONTROL to get rid of that and see if that fixes your issue.

If so, you'll have to place the user in a database role or deny them the explicit privileges against the table.

Unfortunately, you cannot force the ordering of columns in a mysqldump. You can, however, use the table INFORMATION_SCHEMA.COLUMNS. You will need the following:

• MySQL Instance with the old data loaded
• MySQL Instance with the new data loaded
• Some Patience and Scripting

With this setup in mind, here is what you need to do:

STEP 01) Use Query to Present Columns Ordered Per Database/Table

Here is the Query:

SELECT CONCAT(table_schema,'.',table_name),
GROUP_CONCAT(column_name ORDER BY column_name)
FROM information_schema.columns WHERE table_schema NOT IN
('information_schema','performance_schema')
GROUP BY table_schema,table_name;

This will give you every table followed by a CSV list of alphabetically-sorted columns

STEP 02) Launch this Column Query From Both MySQL Instances

IPADDR_OLD=10.1.20.30
IPADDR_NEW=10.1.20.40
SQLSTMT="SELECT CONCAT(table_schema,'.',table_name),"
SQLSTMT="${SQLSTMT} GROUP_CONCAT(column_name ORDER BY column_name)"
SQLSTMT="${SQLSTMT} FROM information_schema.columns WHERE table_schema NOT IN"
SQLSTMT="${SQLSTMT} ('information_schema','performance_schema')"
SQLSTMT="${SQLSTMT} GROUP BY table_schema,table_name"
mysql -u... -p... -h${IPADDR_OLD} -ANe"${SQLSTMT}"  > column_listing1.txt
mysql -u... -p... -h${IPADDR_NEW} -ANe"${SQLSTMT}" >> column_listing2.txt
cat column_listing1.txt  > column_listing.txt
cat column_listing2.txt >> column_listing.txt

Run the Column Query and Collect the Results in column_listing.txt

STEP 03) Perform Unique Sort ; Check For Duplicate Table Names

sort -u < column_listing.txt > column_listing.unq
UNQ_LINES=`wc -l < column_listing.unq`
TXT_LINES=`wc -l < column_listing.txt`
(( DIF_LINES = (UNQ_LINES + UNQ_LINES - TXT_LINES) / 2))
echo ${DIF_LINES}

If everything is identical, DIF_LINES should 0. Otherwise, there are duplicates present.

STEP 04) If There Are Duplicates, Find Them

diff column_listing1.txt column_listing2.txt

Give it a Try !!!

UPDATE 2013-03-22 13:04 EDT

You can also check other metadata tables such as

TABLE_CONSTRAINTS

mysql> desc TABLE_CONSTRAINTS;
+--------------------+--------------+------+-----+---------+-------+
| Field              | Type         | Null | Key | Default | Extra |
+--------------------+--------------+------+-----+---------+-------+
| CONSTRAINT_CATALOG | varchar(512) | NO   |     |         |       |
| CONSTRAINT_SCHEMA  | varchar(64)  | NO   |     |         |       |
| CONSTRAINT_NAME    | varchar(64)  | NO   |     |         |       |
| TABLE_SCHEMA       | varchar(64)  | NO   |     |         |       |
| TABLE_NAME         | varchar(64)  | NO   |     |         |       |
| CONSTRAINT_TYPE    | varchar(64)  | NO   |     |         |       |
+--------------------+--------------+------+-----+---------+-------+
6 rows in set (0.01 sec)

STATISTICS

mysql> desc STATISTICS;
+---------------+---------------+------+-----+---------+-------+
| Field         | Type          | Null | Key | Default | Extra |
+---------------+---------------+------+-----+---------+-------+
| TABLE_CATALOG | varchar(512)  | NO   |     |         |       |
| TABLE_SCHEMA  | varchar(64)   | NO   |     |         |       |
| TABLE_NAME    | varchar(64)   | NO   |     |         |       |
| NON_UNIQUE    | bigint(1)     | NO   |     | 0       |       |
| INDEX_SCHEMA  | varchar(64)   | NO   |     |         |       |
| INDEX_NAME    | varchar(64)   | NO   |     |         |       |
| SEQ_IN_INDEX  | bigint(2)     | NO   |     | 0       |       |
| COLUMN_NAME   | varchar(64)   | NO   |     |         |       |
| COLLATION     | varchar(1)    | YES  |     | NULL    |       |
| CARDINALITY   | bigint(21)    | YES  |     | NULL    |       |
| SUB_PART      | bigint(3)     | YES  |     | NULL    |       |
| PACKED        | varchar(10)   | YES  |     | NULL    |       |
| NULLABLE      | varchar(3)    | NO   |     |         |       |
| INDEX_TYPE    | varchar(16)   | NO   |     |         |       |
| COMMENT       | varchar(16)   | YES  |     | NULL    |       |
| INDEX_COMMENT | varchar(1024) | NO   |     |         |       |
+---------------+---------------+------+-----+---------+-------+
16 rows in set (0.01 sec)

REFERENTIAL_CONSTRAINTS

mysql> desc REFERENTIAL_CONSTRAINTS;
+---------------------------+--------------+------+-----+---------+-------+
| Field                     | Type         | Null | Key | Default | Extra |
+---------------------------+--------------+------+-----+---------+-------+
| CONSTRAINT_CATALOG        | varchar(512) | NO   |     |         |       |
| CONSTRAINT_SCHEMA         | varchar(64)  | NO   |     |         |       |
| CONSTRAINT_NAME           | varchar(64)  | NO   |     |         |       |
| UNIQUE_CONSTRAINT_CATALOG | varchar(512) | NO   |     |         |       |
| UNIQUE_CONSTRAINT_SCHEMA  | varchar(64)  | NO   |     |         |       |
| UNIQUE_CONSTRAINT_NAME    | varchar(64)  | YES  |     | NULL    |       |
| MATCH_OPTION              | varchar(64)  | NO   |     |         |       |
| UPDATE_RULE               | varchar(64)  | NO   |     |         |       |
| DELETE_RULE               | varchar(64)  | NO   |     |         |       |
| TABLE_NAME                | varchar(64)  | NO   |     |         |       |
| REFERENCED_TABLE_NAME     | varchar(64)  | NO   |     |         |       |
+---------------------------+--------------+------+-----+---------+-------+
11 rows in set (0.01 sec)

mysql>

Setup queries that perform the same styled comparison