MacOS – Screenshots won’t be saved after System language change

You could either edit property lists that store the setting and reopen the DictationIM process:

#!/bin/bash

k="com.apple.speech.recognition.AppleSpeechRecognition.prefs DictationIMLocaleIdentifier"
if [[ "$(defaults read $k)" == en-US ]]; then
  defaults write $k fr-FR
  defaults write com.apple.assistant "Session Language" fr-FR
else
  defaults write $k en-US 
  defaults write com.apple.assistant "Session Language" en-US
fi
killall -HUP DictationIM

Or use UI scripting:

tell application "System Preferences"
    reveal anchor "Dictation" of pane "com.apple.preference.speech"
end tell
tell application "System Events" to tell process "System Preferences"
    tell pop up button 1 of tab group 1 of window 1
        click
        if value is "English (United States)" then
            click menu item "French" of menu 1
        else
            click menu item "English (United States)" of menu 1
        end if
    end tell
end tell
quit application "System Preferences"

Both scripts are copied from my answer to How to use applescript to toggle the language setting of new dictation tool (10.8) - Stack Overflow.

Works for me quite happily.

Have you restarted UIserver?

killall SystemUIServer

Does the path exist?

UPDATE: If the screen capture cannot find or write to the designated folder, it will default to the current user's desktop.