MacOS – List all programs without any window and kill them

"Connection is invalid" means that the script cannot communicate with the application. Perhaps it has been quit during execution… perhaps there is a duplication in your list? My best guess is that there is more than one process spawned by an application.

Anyway, I think your methodology could be improved. One of your problems is that you're checking the process for each item in your list. You should compile a list of processes, and check that. This avoids the problem of duplicate processes for the same application. It also deals with the issue of the process list changing during script execution.

set appList to {"Caffeine", ...}

tell application "System Events" 
    set procList to (name of every process)
end tell

repeat with appName in appList
    if (procList contains appName) is true then
        tell application appName to quit
    else
        tell application appName to activate
    end if
end repeat

If you still get errors, you might have to enclose the tell application statements in try blocks.

One more thing: the approach you're taking doesn't work well if only some of the applications are open, and some are not. You're checking each individually and quitting if it's open, launching if it's not. So your list of applications will still be split between open/shut down. It sounds like you want to open a "set" of applications and close a "set" of applications using the same script.

Therefore, you may want to consider splitting this into two scripts, "open set" and "quit set", and/or checking whether your "main" application is open and cascading the open/close of your application list depending on that one application's state.

Have you tried using the built in tools to force a log out upon reaching a certain idle time?

It is an Advanced Option (see the bottom button) in the Security & Privacy preference pane on Lion.

If you want one user to have a different timeout you can script things easily with Automator or AppleScript:

tell application "System Events"
    log out
end tell

The trick is making your custom app keep a timer for 30 minutes of inactivity which is why the system control panel is the best option for this request.