Is it possible to dual boot Windows 7 (on my internal disk) and OS X Mountain Lion using two different drives?
MacOS – How to dual boot Windows 7 and OS X Mountain Lion on two separate drives
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Best Answer
Windows on internal, OS X on external
Use Internet Recovery (boot with ⌘⌥R) to obtain an install media, then select your external disk as the install destination.
You can do a normal ⌥-boot and select your external disk as the boot drive, which will boot into OS X.
OS X on internal, Windows on external
You can't use Boot Camp with an external disk, per the official user guide:
Source: http://manuals.info.apple.com/MANUALS/1000/MA1583/en_US/boot_camp_install-setup_10.7.pdf
However, you might succeed by creating a Boot Camp partition on the internal disk, then cloning the partition to an external drive. Once the clone is done, you can delete the Boot Camp partition from the internal disk and extend your OS X partition.