MacOS – disable the windows key in parallels 14

According to this article on macosxhints you can press ctrl-alt to get AltGr. Sometimes that doesn't work, so you'll have to remap your keys under windows, which is described in the linked to article.

There's also this article on Parallels' forums which suggests you do this:

1. Stop any running VMs, close all instances of Parallels Desktop for Mac.
2. Launch “Macintosh HD” - “Applications” – “Utilities” – “Terminal”.
3. Type the following commands in Terminal (without quotes), please mind that the system might ask you for the Administrator password after each command – type it and hit Enter:
4. “sudo touch /Library/Parallels/.keyboard_config”
5. “sudo chmod 666 /Library/Parallels/.keyboard_config”
6. “sudo echo "numenterisaltgr" > /Library/Parallels/.keyboard_config”
7. Close the Terminal.
8. Launch Parallels Desktop for Mac and check Right Enter key behavior in VM – everything should work as you’ve set.

Power off your VM, open Parallels Desktop, select the VM you wish to modify then in the menu bar select Virtual Machine -> Configure...

You'll get a Options window where you can change all the settings of the VM. Specifically to your application problem, you can modify those settings underneath Options -> Applications. I'd uncheck "Share Windows applications with Mac".

After completing that step you'll need to manually rebuild the LaunchServices database. Open Terminal and run the following (without the $):

 $ /System/Library/Frameworks/CoreServices.framework/Frameworks/LaunchServices.framework/Support/lsregister -kill -r -domain local -domain system -domain user
 $ killall Finder