I have set up my Gmail account to send and receive messages from my business email address over Exchange on my iPhone 4S. I receive all messages fine, but it doesn't send messages from my business email address unless I am logged into Gmail in a web browser.
IPhone – How to set up Gmail on the iPhone 4S with Exchange
exchange-activesyncgmailiphone
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Best Answer
http://support.google.com/mobile/bin/answer.py?hl=en&topic=14252&answer=138740
The only thing to notice is the m.google.com server address.