How to force all traffic for a single app through VPN / Proxy + Open Source? aka App Firewall

You need a firewall between you and the Internet that will block all traffic except traffic to the IP address of your VPN host

Your router will more than likely have this functionality built in

Step 1, create two plain text files named ip-up and ip-down in /etc/ppp and make the two files executable:

$ sudo touch /etc/ppp/ip-{up,down}
$ sudo chmod +x /etc/ppp/ip-{up,down}

Step 2, modify the file ip-up, add the following:

#!/bin/sh
export PATH="/bin:/sbin:/usr/sbin:/usr/bin"

OLDGW=`netstat -nr | grep '^default' | grep -v 'ppp' | sed 's/default *\([0-9\.]*\) .*/\1/'`

if [ ! -e /tmp/pptp_oldgw ]; then
    echo "${OLDGW}" > /tmp/pptp_oldgw
fi

dscacheutil -flushcache
route add 10.4.0.0/24 "${OLDGW}"

Step 3, modify the ip-down, add the following:

#!/bin/sh
export PATH="/bin:/sbin:/usr/sbin:/usr/bin"

if [ ! -e /tmp/pptp_oldgw ]; then
        exit 0
fi

ODLGW=`cat /tmp/pptp_oldgw`

route delete 10.4.0.0/24 "${OLDGW}"
rm /tmp/pptp_oldgw