You can simply let the Safari membership term run out, as it doesn't look like Apple has given people an easy way to do this. Your best bet at cancelling it immediately though is to call Apple directly at 1-800-633-2152 and ask for them to cancel it.
A few things to check.
You said you uninstalled your extensions. Are they definitely gone? Check the following folder. It should be empty except for an Extensions.plist file.
/Users/YOURUSERNAME/Library/Safari/Extensions
You mentioned extensions but not plugins. Within Safari's preferences go to the Security tab and click on the button "Website Settings..." beside "Internet plug-ins". Uncheck anything you don't recognise there and try again. Especially, obviously, anything enabled for Google's sites.
Another thing to check is the proxy settings on your Mac. A quick way to access these is from the Advanced tab in Safari's preferences. There should be a "Change Settings..." button beside "Proxies" near the bottom of that tab that will launch System Preferences and take you right to the proxy settings. Hard to give you guidance beyond this, but look for any proxy settings that you haven't configured yourself.
One last thing to check for is malicious or buggy kernel extensions. While it's unlikely on Yosemite (as kernel extensions now need to be signed to load) it might be worth checking anyway. Open the Terminal application and type the following command it will list any kernel extensions that don't identify as coming from Apple.
kextstat | grep -v "com.apple"
Failing that a useful tool to help people diagnose problems is EtreCheck. Download and run it and paste the output into a Gist and update your question with the link.
Best Answer
Apple unified all the developer programs (iOS, Mac and Safari) under one umbrella program entitled Apple Developer Program. This is what you need to enrol with to obtain a certificate for Safari extensions.